四氯化碳催化加氢研究进展

化工进展

四氯化碳催化加氢研究进展

张东宝，朱建军，单玉华，李明时

江苏工业学院化工系江苏省精细石油化工重点实验室

出版日期:2007-04-25 发布日期:2007-04-25

Advances in hydrodechlorination of carbon tetrachloride

ZHANG Dongbao，ZHU Jianjun，SHAN Yuhua，LI Mingshi

Department of Chemical Engineering，Jiangsu Province key Laboratory of Fine Petrochemicals，Jiangsu Polytechnic University

Online:2007-04-25 Published:2007-04-25

摘要/Abstract

摘要： 从四氯化碳选择性加氢脱氯催化剂的活性组分、反应机理和催化剂失活及预处理等方面详细介绍了四氯化碳选择性加氢脱氯反应及催化剂的最新研究进展，简述了反应温度、压力和n(H2)/n(CCl4)比对四氯化碳催化加氢产品分布的影响，并指出了四氯化碳选择性加氢脱氯反应的发展方向。

Abstract: Hydrodechlorination(HDC) of CCl4 to CHCl3 is an economically and environmentally attractive alternative for CCl4 disposal. This review deals with the recent progress of catalytic hydrodechlorination of carbon tetrachloride，including active components，deactivation and pretreatment of catalysts and reaction mechanism. The influence of reaction temperature，pressure and H2/CCl4 molar ratio on the distribution of products of hydrodechlorination reaction of CCl4 is discussed. The future trend in the development of hydrodechlorination of carbon tetrachloride is presented.

张东宝，朱建军，单玉华，李明时. 四氯化碳催化加氢研究进展 [J]. 化工进展.

ZHANG Dongbao，ZHU Jianjun，SHAN Yuhua，LI Mingshi. Advances in hydrodechlorination of carbon tetrachloride[J]. Chemical Industry and Engineering Progree.