荧光水凝胶基信息储存材料的构筑及其加密性能研究进展

doi:10.16085/j.issn.1000-6613.2023-1417

化工进展 ›› 2024, Vol. 43 ›› Issue (9): 5013-5025.DOI: 10.16085/j.issn.1000-6613.2023-1417

• 材料科学与技术 • 上一篇

荧光水凝胶基信息储存材料的构筑及其加密性能研究进展

郝康安¹(), 周颖², 刘川¹, 俞润昊², 黄安荣³, 吴翀⁴, 左晓玲²()

^1.贵州民族大学物理与机电工程学院，贵州贵阳 550025
^2.贵州民族大学材料科学与工程学院，贵州贵阳 550025
^3.贵州省材料产业技术研究院国家复合改性聚合物材料工程技术研究中心，贵州贵阳 550025
^4.贵州中医药大学药学院，贵州贵阳 550025

收稿日期:2023-08-14 修回日期:2023-10-30 出版日期:2024-09-15 发布日期:2024-09-30
通讯作者: 左晓玲
作者简介:郝康安（1999—），男，硕士研究生，研究方向为荧光水凝胶基信息储存材料的制备及其加密性能。E-mail：haokangansai@126.com。
基金资助:
国家自然基金青年基金(12304482);贵州省科学技术基金（黔科合基础 ZK[2022]重点029,黔科合支撑项目([2020]4Y107);4D打印智能材料科技创新人才团队项目（GZMUZK[2003]CXTD01）

Recent advances in the construction and encryption properties of fluorescent hydrogel-based information storage materials

HAO Kang’an¹(), ZHOU Ying², LIU Chuan¹, YU Runhao², HUANG Anrong³, WU Chong⁴, ZUO Xiaoling²()

^1.College of Physics and Mechanical and Electrical Engineering, Guizhou Minzu University, Guiyang 550025, Guizhou, China
^2.College of Materials Science and Engineering, Guizhou Minzu University, Guiyang 550025, Guizhou, China
^3.National Engineering and Technology Research Center of Composite Modified Polymer Materials, Guizhou Material Industrial Technology Research Institute, Guiyang 550025, Guizhou, China
^4.College of Pharmacy, Guizhou University of Traditional Chinese Medicine, Guiyang 550025, Guizhou, China

Received:2023-08-14 Revised:2023-10-30 Online:2024-09-15 Published:2024-09-30
Contact: ZUO Xiaoling

摘要/Abstract

摘要：

基于传统储存介质的信息常常以静态形式显现，无法面对当下伪造、仿制技术带来的挑战。因此，荧光水凝胶——一类具有优异的刺激响应发光特性，结构和功能易于设计和调控的智能响应类“软材料”，由于其能够在特定的外界刺激下呈现颜色的变化或者形状的改变，因而在信息安全和防伪领域引起了广泛的研究兴趣。本文概述了荧光水凝胶基信息储存材料的构筑历程，详细归纳了信息加密与保护模式从单级加密到多级加密（三维加密平台和迷惑信息加密）模式，再到具有时变效应的动态加密模式的阶段性演变。最后，就荧光水凝胶的构筑方法和信息加密应用方面，深入讨论了其面临的挑战、机遇和未来发展前景。本综述旨在促进荧光水凝胶基信息储存材料及其加密性能的进一步发展，为未来更智能、安全型信息加密体系的研发提供思路。

关键词: 荧光水凝胶, 刺激响应性, 信息储存材料, 多级加密, 动态加密

Abstract:

Traditional storage media presents information in a static form, making it vulnerable to counterfeiting and imitation. To address this issue, researchers have turned to fluorescent hydrogels, a type of "soft material" that exhibits excellent luminescence characteristics and can be easily designed and regulated. These materials are of particular interest in the field of information security and anti-counterfeiting due to their ability to change color or shape in response to specific external stimuli. By incorporating fluorescent hydrogels into products or packaging, it is possible to create dynamic and interactive features that are difficult to replicate or manipulate, offering a more secure solution than traditional static storage media. Based on these, this literature summarized the construction progress of fluorescent hydrogel-based information storage materials, concluded the phased evolution in the patterns of information encryption and protection varying from the single level encryption to the multilevel encryption (3D encryption platform and confusing information encryption), and then to the dynamic encryption patterns with time-varying effects. Last but not least, the challenges, opportunities and future development prospects of fluorescent hydrogels were discussed in terms of the construction methods and information encryption applications. The purpose of this review was to promote the further development of fluorescent hydrogel-based information storage materials and their encryption properties, providing insights for the future development of more intelligent and secure information encryption systems.

Key words: fluorescent hydrogels, stimulus responsiveness, information storage materials, multilevel encryption, dynamic encryption

中图分类号:

TQ311

郝康安, 周颖, 刘川, 俞润昊, 黄安荣, 吴翀, 左晓玲. 荧光水凝胶基信息储存材料的构筑及其加密性能研究进展[J]. 化工进展, 2024, 43(9): 5013-5025.

HAO Kang’an, ZHOU Ying, LIU Chuan, YU Runhao, HUANG Anrong, WU Chong, ZUO Xiaoling. Recent advances in the construction and encryption properties of fluorescent hydrogel-based information storage materials[J]. Chemical Industry and Engineering Progress, 2024, 43(9): 5013-5025.

图/表 9

图1 荧光水凝胶基信息储存材料加密模式概括

图2 单级加密模式示意图

图3 荧光水凝胶P(VI-co-MAAc)的合成及加密过程[43]

图4 3D水凝胶矩阵的制备过程及加密解密方案[46]

图5 PANT水凝胶的合成及加密解密方案[18]

图6 迷惑信息加密法用于荧光水凝胶基信息存储材料[50]

图7 基于多种加密形式共存的水凝胶基信息加密平台[53]

图8 TPE3N3+-水凝胶/ PAAc-水凝胶双层水凝胶机理与加密解密示意图[55]

图9 L-AM x -BIS y 水凝胶和U-AM x -BIS y 水凝胶的构建及加密模式示意图[58]

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荧光水凝胶基信息储存材料的构筑及其加密性能研究进展

Recent advances in the construction and encryption properties of fluorescent hydrogel-based information storage materials

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