浮式氢能储运过程中FLH2通道管外降膜流动的海上适应性强化机理

doi:10.16085/j.issn.1000-6613.2023-1123

化工进展 ›› 2024, Vol. 43 ›› Issue (1): 338-352.DOI: 10.16085/j.issn.1000-6613.2023-1123

• 专栏：化工过程强化 • 上一篇

浮式氢能储运过程中FLH₂通道管外降膜流动的海上适应性强化机理

孙崇正¹(), 李玉星², 许洁³, 韩辉², 宋光春², 卢晓¹()

^1.山东科技大学储能技术学院，山东青岛 266590
^2.中国石油大学(华东)储运与建筑工程学院，山东省油气储运安全重点实验室，山东青岛 266580
^3.国家管网集团北京管道有限公司，北京 100101

收稿日期:2023-07-06 修回日期:2023-10-27 出版日期:2024-01-20 发布日期:2024-02-05
通讯作者: 卢晓
作者简介:孙崇正（1993—），男，博士，讲师，研究方向为氢能高效储存与利用。E-mail：sdkjdxscz@163.com。
基金资助:
国家自然科学基金(52304067);山东省自然科学基金(ZR2021QE073);中国博士后科学基金(2023M732111)

Offshore adaptability enhancement mechanism of falling film flow outside the FLH₂ channel tube during floating hydrogen energy storage and transportation

SUN Chongzheng¹(), LI Yuxing², XU Jie³, HAN Hui², SONG Guangchun², LU Xiao¹()

^1.College of Energy Storage Technology, Shandong University of Science and Technology, Qingdao 266590, Shandong, China
^2.College of Pipeline and Civil Engineering，Shandong Provincial Key Laboratory of Oil & Gas Storage and Transportation Safety, China University of Petroleum (East China), Qingdao 266580, Shandong, China
^3.PipeChina Beijing Pipeline Company, Beijing 100101, China

Received:2023-07-06 Revised:2023-10-27 Online:2024-01-20 Published:2024-02-05
Contact: LU Xiao

摘要/Abstract

摘要：

随着海上风电和天然气制氢技术的发展，以氢能作为媒介的深海能源互联互通体系正不断完善。液态氢储运是实现海上氢能大规模运输和利用的有效方法，揭示海况条件下降膜流动机理是实现浮式氢能高效储运的关键。本文基于高速摄像系统和晃荡平台系统，同时基于耦合的VOF和Level Set两相流模型和动网格技术，采用浮式微观可视化实验和数值模拟相结合的方法，研究氢能储运过程中FLH₂（浮式氢气液化装置）换热通道管外降膜流动的海上适应性强化机理。研究结果表明，与常规光圆管、螺纹波管和方波管相比，波纹管管外降膜流动的液膜均匀性较好。在海况下波纹管间降膜流动流型稳定，并且均未出现管壁表面干涸的现象，因此在浮式氢气液化装置FLH₂中推荐采用波纹管以强化其海上适应性。基于可视化实验和数值模拟结果，得到了降膜流动的流型演化规律，并拟合了波纹管外降膜流动的液膜厚度计算关联式。

关键词: 氢气储运, 降膜流动, 海上适应性, 强化机理

Abstract:

With the development of hydrogen production technology from offshore wind power and natural gas, the deep-sea energy interconnection system using hydrogen energy as the medium is constantly improving. Liquid hydrogen storage and transportation is an effective method for large-scale transportation and utilization of offshore hydrogen energy. Revealing the mechanism of falling film flow under offshore sloshing conditions is the key to realize efficient storage and transportation of floating hydrogen energy. In this paper, the method of floating visualization experiment and numerical simulation is conducted to reveal the offshore adaptability enhancement mechanism of falling film flow outside the FLH₂ (floating hydrogen liquefaction unit) channel tube during floating hydrogen energy storage and transportation, based on high-speed camera technology and sloshing platform, the coupled VOF and Level Set two-phase flow model and moving grid technology. The results show that the liquid film uniformity of the falling film flow outside the corrugated tube is better than the conventional circular tube, spiral grooved tube and square corrugated tube. Under the offshore conditions, the flow pattern of corrugated tube is stable, and the dry patch of corrugated tube surface does not appear. It is recommended to use the corrugated tube in the floating hydrogen liquefaction unit. Based on visual experiments and numerical simulation results, the evolution law of falling film flow pattern and a calculation correlation for film thickness of corrugated tube are obtained.

Key words: hydrogen storage and transportation, falling film flow, offshore adaptability, enhancement mechanism

中图分类号:

TE646

孙崇正, 李玉星, 许洁, 韩辉, 宋光春, 卢晓. 浮式氢能储运过程中FLH₂通道管外降膜流动的海上适应性强化机理[J]. 化工进展, 2024, 43(1): 338-352.

SUN Chongzheng, LI Yuxing, XU Jie, HAN Hui, SONG Guangchun, LU Xiao. Offshore adaptability enhancement mechanism of falling film flow outside the FLH₂ channel tube during floating hydrogen energy storage and transportation[J]. Chemical Industry and Engineering Progress, 2024, 43(1): 338-352.

图/表 23

图1 降膜流动浮式微观可视化实验流程(a)与设备实物图(b)

图2 降膜流动可视化实验测试3D打印管

图3 不同结构的管外降膜流动流型划分

图4 水平静止条件下光圆管外降膜流动状态

图5 海况3°条件下光圆管外降膜流动状态

图6 海况6°条件下光圆管外降膜流动状态

图7 海况9°条件下光圆管外降膜流动状态

图8 水平静止条件下方波管外降膜流动状态

图9 海况9°条件下方波管外降膜流动状态

图10 水平静止条件下螺纹波管外降膜流动状态

图11 海况6°条件下螺纹波管外降膜流动状态

图12 水平静止条件下波纹管外降膜流动状态

图13 海况6°条件下波纹管外降膜流动状态

图14 海况9°条件下波纹管外降膜流动状态

图15 网格划分示意图

图16 降膜流动流型模拟结果与实验结果对比

图17 海况6°条件下光圆管外降膜流动随时间变化过程

图18 水平静止条件下波纹管外降膜流动随时间变化过程

图19 海况6°条件下波纹管外降膜流动随时间变化过程

图20 海况9°条件下波纹管外降膜流动随时间变化过程

图21 不同条件下波纹管外降膜流动液膜厚度分布

图22 优化后理论计算关联式的波纹管液膜厚度与模拟值对比

图23 海况下理论计算关联式的波纹管液膜厚度与模拟值对比

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浮式氢能储运过程中FLH₂通道管外降膜流动的海上适应性强化机理

Offshore adaptability enhancement mechanism of falling film flow outside the FLH₂ channel tube during floating hydrogen energy storage and transportation

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