Abstract:

Zeolitic imidazolate frameworks（ZIFs）are imidazole-containing coordination polymers of metal-organic framework（MOFs）materials. These materials have attracted much attention for their composition diversity，higher thermal and chemical stability and excellent selectivity for carbon dioxide capture. This review briefly summarizes the progress of these special MOFs materials for gas storage and separation，magnetic property and catalysis. In addition，prospects in the synthesis and application of these materials are also discussed.

摘要：

沸石咪唑酯骨架结构材料（ZIFs）是一类以咪唑或其衍生物为配体的特殊金属有机骨架结构材料（MOFs），因其结构多样性、高度的热学和化学稳定性及高效捕获和存储CO₂ 等性能，近几年受到国内外研究者的广泛关注。本文对含咪唑基配体材料的合成和发展现状进行了综述；总结了这种材料在气体的存储和分离、磁性、催化等方面的性能，并对这种新型材料在设计、合成与应用中的广阔前景作了展望。