Advances in research on V2O5/TiO2 catalysts for the gas-phase oxidation of 3-picoline to nicotinic acid

doi:10.16085/j.issn.1000-6613.2016.04.021

Abstract

Abstract: Nicotinic acid has been widely used in different fields as the important chemical and pharmaceutical intermediate.Compared with other traditional technology for production of nicotinic acid, one-step gas phase oxidation of 3-picoline has remarkable advantages of low cost, easy product separation, high product quality and few pollution.The oxidative reaction of 3-picoline on V₂O₅/TiO₂ catalysts had rather high activity.Thus the paper reviews the recent research progress of oxidation 3-picoline to nicotinic acid on V₂O₅/TiO₂ catalysts. It analyzed the surface structures of the catalysts by carrier and the influence factors from the preparation methods, loading content of V₂O₅, calcination temperature and time and doping additives. It also discussed the effects of interactions among various catalytic species, and the mechanism of the catalytic reaction. Defects of low reaction rate and selectivity, narrow temperature window and the heat of exothermic reaction were also explained. Finally, the application perspective and future development in the field of V₂O₅/TiO₂ catalysts and the reactor design were explored.

Key words: gas-phase, catalysis, oxidation, 3-picoline, synthesis, nicotinic acid, V₂O₅/TiO₂ catalyst

摘要： 烟酸作为重要的化工和医药中间体广泛应用于不同领域.相较于传统工艺,3-甲基吡啶气相一步催化氧化合成烟酸的方法具有成本低、污染低、产品质量高等优点,展现出良好的应用前景.目前V₂O₅/TiO₂系列催化剂在3-甲基吡啶的氧化反应中表现出了良好的氧化活性.本文主要分析了催化剂表面的VO_x结构,并概述了载体、制备方法、负载量、焙烧过程和助剂掺杂对结构的影响,探讨催化剂中各组分之间的相互作用,根据相关文献推测3-甲基吡啶氧化的反应机理.但该类催化剂仍然存在反应速率和选择性较低、温度窗口窄、反应过程中放出的热量对催化剂的影响等一些技术问题.文章从催化剂的开发和反应器的设计两方面进行了展望.

关键词: 气相, 催化, 氧化, 3-甲基吡啶, 合成, 烟酸, 钒钛催化剂

CLC Number:

TQ032.4

HU Xiaobo, YUAN Weijie, ZHU Qiulian, CHEN Yinfei, LU Hanfeng. Advances in research on V₂O₅/TiO₂ catalysts for the gas-phase oxidation of 3-picoline to nicotinic acid[J]. Chemical Industry and Engineering Progree, 2016, 35(04): 1101-1106.

胡小波, 袁伟杰, 朱秋莲, 陈银飞, 卢晗锋. 3-甲基吡啶一步气相氧化合成烟酸的V₂O₅/TiO₂催化剂研究进展[J]. 化工进展, 2016, 35(04): 1101-1106.

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Advances in research on V₂O₅/TiO₂ catalysts for the gas-phase oxidation of 3-picoline to nicotinic acid

3-甲基吡啶一步气相氧化合成烟酸的V₂O₅/TiO₂催化剂研究进展

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