Abstract:

Ring-opening polymerization of aliphatic cyclic carbonate is an important method for preparing aliphatic polycarbonates，which is one important class of biomedical materials. This review presents a review on the synthesis and ring-opening polymerization of aliphatic cyclic carbonate with different sizes and types. Mechanisms of cationic，anionic and coordination ring-opening polymerization of cyclic carbonates are discussed.

摘要：

脂肪族聚碳酸酯是生物医用材料中的一个重要组成部分，而脂肪族环状碳酸酯开环聚合是制备脂肪族聚碳酸酯的一类重要方法。本文介绍了近年来不同大小和种类的脂肪族环状碳酸酯单体的合成及其聚合物的制备，并对其阳离子开环聚合、阴离子开环聚合和配位聚合的机理进行了讨论。