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Advances in catalytic mechanisms and kinetics of propane dehydrogenation

LIU Shuhe,FANG Xiangchen,ZHANG Xiwen,ZHANG Haijuan   

  1. School of Chemistry & Material science,Liaoning University of Petroleum & Chemical Technology;Fushun Research Institute of Petroleum and Petrochemicals
  • Online:2009-02-05 Published:2009-02-05

丙烷脱氢催化反应机理及动力学研究进展

刘淑鹤,方向晨,张喜文,张海娟   

  1. 辽宁石油化工大学化学与材料科学学院;抚顺石油化工研究院

Abstract: The non-oxidative and oxidative dehydrogenation of propane to propylene based on the principles of chemical reaction,thermodynamics,catalysts is summarized.The mechanisms and kinetics of dehydrogenation reaction over Pt,Cr or ZSM-5 zeolite catalysts,and oxidative dehydrogenation over V-Mg-O and V2O5/ZrO2 catalysts are discussed in detail.

摘要: 从化学反应原理、热力学性质和催化剂等角度出发,概述了丙烷无氧脱氢和有氧脱氢的反应体系;详述了无氧脱氢催化剂体系中的Pt系、Cr系和ZSM-5分子筛催化剂、氧化脱氢催化剂体系中的钒基催化剂V-Mg-O,V2O5/ZrO2上的脱氢反应机理和动力学研究。

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