Abstract: The advances in hydrothermal synthesis, characterization of heteroatom-containing molecular sieves and mechanisms of template are summarized. The applications of heteroatom-containing molecular sieves to hydroxylation, alkylation, epoxidation, cracking reaction, etc. for their good catalytic performance and selective oxidation properties are introduced in detail. The present situation of the application of the heteroatom-containing molecular sieves in chemical industry is reviewed, and the problems in their synthesis and application are analyzed.

摘要： 综述了杂原子分子筛如杂原子ZSM-5微孔分子筛、杂原子MCM-41中孔分子筛及其他杂原子分子筛的水热合成、表征方法、模板剂作用机理。详细分析和归纳了杂原子分子筛因具有较好的催化性能和选择性氧化性能，而用于羟基化、烷基化、环氧化、裂化等反应中的研究进展情况。最后对杂原子分子筛的应用前景进行了展望，并对其合成和应用存在的问题进行了分析。