Abstract: In this paper，a series of hexaaluminate oxides LaMAl11O19-δ（M＝Fe，Co，Ni，Mn and Cu）were prepared by decomposition of nitrates and calcination at a high temperature . The structure and properties of the catalysts LaMAl11O19-δ were characterized with XRD，XPS，TPR，SAA and TGA techniques. The hexaaluminate oxides obtained by the method of pyrolysis exhibited the same crystal structure. In other words，hexaaluminate oxides LaMAl11O19-δ（M＝Fe，Co，Ni，Mn and Cu）took on nicer stability and catalytic activity for partial oxidation of methane producing synthesis gas. At the same time，the sequence of catalytic activity of transition metal M for the topic reaction was Cu

摘要： 采用高温分解法，通过过渡金属M（M＝Fe、Co、Ni、Mn和Cu）的晶格取代，制备了一系列新型六铝酸盐复合氧化物催化剂，并通过XRD、XPS、TPR、SAA、TGA等测试手段对催化剂的结构和性质进行了表征，并考察了其甲烷部分氧化制合成气反应的催化活性。实验结果表明，相同M取代系列六铝酸盐中过渡金属活性顺序均为Cu