Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (8): 4238-4246.DOI: 10.16085/j.issn.1000-6613.2022-1820
• Energy processes and technology • Previous Articles Next Articles
LI Dong1,2(), WANG Qianqian1,2, ZHANG Liang1,2(), LI Jun1,2, FU Qian1,2, ZHU Xun1,2, LIAO Qiang1,2
Received:
2022-09-29
Revised:
2023-01-17
Online:
2023-09-19
Published:
2023-08-15
Contact:
ZHANG Liang
李洞1,2(), 王倩倩1,2, 张亮1,2(), 李俊1,2, 付乾1,2, 朱恂1,2, 廖强1,2
通讯作者:
张亮
作者简介:
李洞(1998—),男,硕士研究生,研究方向为电化学能源转换。E-mail:20173242@cqu.edu.cn。
基金资助:
CLC Number:
LI Dong, WANG Qianqian, ZHANG Liang, LI Jun, FU Qian, ZHU Xun, LIAO Qiang. Performance of series stack of non-aqueous nano slurry thermally regenerative flow batteries[J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4238-4246.
李洞, 王倩倩, 张亮, 李俊, 付乾, 朱恂, 廖强. 非水系纳米流体热再生液流电池串联堆性能特性[J]. 化工进展, 2023, 42(8): 4238-4246.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-1820
参数 | 数值 |
---|---|
电极高度H/mm | 20 |
电极宽度W/mm | 20 |
腔室及电极厚度L/mm | 3 |
AEM厚度T/mm | 0.1 |
参数 | 数值 |
---|---|
电极高度H/mm | 20 |
电极宽度W/mm | 20 |
腔室及电极厚度L/mm | 3 |
AEM厚度T/mm | 0.1 |
参数 | 数值 | 来源 |
---|---|---|
Cu2+扩散系数D(Cu2+)/m2·s-1 | 1.5×10-9 | 文献[ |
Cu(CH3CN)4+扩散系数D[Cu(CH3CN)4+]/m2·s-1 | 2.4×10-10 | 测量 |
CH3CN扩散系数D(CH3CN)/m2·s-1 | 9.3×10-9 | 文献[ |
Cu扩散系数D(Cu)/m2·s-1 | 1.33×10-9 | 测量 |
BF4-扩散系数D(BF4-)/m2·s-1 | 1.1×10-9 | 文献[ |
电极孔隙率ε | 0.93 | — |
电极活性比表面积aV/m2·m-3 | 3504 | 测量 |
操作温度T/K | 298.15 | 测量 |
阳极反应速度常量K0a/m·s-1 | 2.5×10-7 | 文献[ |
阴极反应速度常量K0c/m·s-1 | 7×10-7 | 文献[ |
Cu2+初始浓度c(Cu2+)/mol·L-1 | 0.1 | — |
CH3CN初始浓度c(CH3CN)/mol·L-1 | 4 | — |
Cu初始浓度c(Cu)/mol·L-1 | 0.1 | — |
BF4-初始浓度c(BF4-)/mol·L-1 | 0.15 | — |
0.55 | — | |
0.45 | — | |
0.55 | — | |
0.45 | — |
参数 | 数值 | 来源 |
---|---|---|
Cu2+扩散系数D(Cu2+)/m2·s-1 | 1.5×10-9 | 文献[ |
Cu(CH3CN)4+扩散系数D[Cu(CH3CN)4+]/m2·s-1 | 2.4×10-10 | 测量 |
CH3CN扩散系数D(CH3CN)/m2·s-1 | 9.3×10-9 | 文献[ |
Cu扩散系数D(Cu)/m2·s-1 | 1.33×10-9 | 测量 |
BF4-扩散系数D(BF4-)/m2·s-1 | 1.1×10-9 | 文献[ |
电极孔隙率ε | 0.93 | — |
电极活性比表面积aV/m2·m-3 | 3504 | 测量 |
操作温度T/K | 298.15 | 测量 |
阳极反应速度常量K0a/m·s-1 | 2.5×10-7 | 文献[ |
阴极反应速度常量K0c/m·s-1 | 7×10-7 | 文献[ |
Cu2+初始浓度c(Cu2+)/mol·L-1 | 0.1 | — |
CH3CN初始浓度c(CH3CN)/mol·L-1 | 4 | — |
Cu初始浓度c(Cu)/mol·L-1 | 0.1 | — |
BF4-初始浓度c(BF4-)/mol·L-1 | 0.15 | — |
0.55 | — | |
0.45 | — | |
0.55 | — | |
0.45 | — |
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