Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (8): 4192-4203.DOI: 10.16085/j.issn.1000-6613.2021-2097
• Industrial catalysis • Previous Articles Next Articles
WU Yushuai(), YOU Qing, DONG Xujie, ZHU Ziqi, WANG Xu, CHEN Huiyong(), MA Xiaoxun
Received:
2021-10-11
Revised:
2022-01-14
Online:
2022-08-22
Published:
2022-08-25
Contact:
CHEN Huiyong
吴玉帅(), 尤晴, 董旭杰, 朱子麒, 王旭, 陈汇勇(), 马晓迅
通讯作者:
陈汇勇
作者简介:
吴玉帅(1998—),男,硕士研究生,研究方向为杂原子掺杂beta分子筛的烯烃环氧化催化性能。E-mail:基金资助:
CLC Number:
WU Yushuai, YOU Qing, DONG Xujie, ZHU Ziqi, WANG Xu, CHEN Huiyong, MA Xiaoxun. Synthesis of heteroatom-substituted beta zeolites for catalytic epoxidation of cyclic olefins[J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4192-4203.
吴玉帅, 尤晴, 董旭杰, 朱子麒, 王旭, 陈汇勇, 马晓迅. 杂原子掺杂beta分子筛的烯烃环氧化催化性能[J]. 化工进展, 2022, 41(8): 4192-4203.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2021-2097
分子筛 | 金属离子 | 金属含量 /μmol·g-1 | 离子半径 /? | 电负性 | 金属-氧键 | 键长 /? |
---|---|---|---|---|---|---|
Ti-beta | Ti4+ | 272 | 0.605 | 1.54 | Ti—O | 1.80 |
V-beta | V5+ | 157 | 0.59 | 1.63 | V—O | 1.755 |
Mo-beta | Mo6+ | 12 | 0.59 | 2.16 | Mo—O | 1.83 |
W-beta | W6+ | 27 | 0.61 | 2.36 | W—O | 1.90 |
分子筛 | 金属离子 | 金属含量 /μmol·g-1 | 离子半径 /? | 电负性 | 金属-氧键 | 键长 /? |
---|---|---|---|---|---|---|
Ti-beta | Ti4+ | 272 | 0.605 | 1.54 | Ti—O | 1.80 |
V-beta | V5+ | 157 | 0.59 | 1.63 | V—O | 1.755 |
Mo-beta | Mo6+ | 12 | 0.59 | 2.16 | Mo—O | 1.83 |
W-beta | W6+ | 27 | 0.61 | 2.36 | W—O | 1.90 |
分子筛 | 微孔比表面积/m2·g-1 | 外比表面积/m2·g-1 | 总比表面积/m2·g-1 | 微孔孔容/cm3·g-1 | 总孔容/cm3·g-1 |
---|---|---|---|---|---|
W-beta | 481 | 67 | 548 | 0.18 | 0.40 |
Mo-beta | 481 | 61 | 542 | 0.17 | 0.35 |
V-beta | 493 | 69 | 561 | 0.19 | 0.40 |
Ti-beta | 500 | 67 | 567 | 0.19 | 0.34 |
分子筛 | 微孔比表面积/m2·g-1 | 外比表面积/m2·g-1 | 总比表面积/m2·g-1 | 微孔孔容/cm3·g-1 | 总孔容/cm3·g-1 |
---|---|---|---|---|---|
W-beta | 481 | 67 | 548 | 0.18 | 0.40 |
Mo-beta | 481 | 61 | 542 | 0.17 | 0.35 |
V-beta | 493 | 69 | 561 | 0.19 | 0.40 |
Ti-beta | 500 | 67 | 567 | 0.19 | 0.34 |
催化剂 | 环己烯 | 环辛烯 | |||||||
转化率/% | 选择性/% | 转换频率(TOF)/h-1 | 转化率/% | 选择性/% | 转换频率(TOF)/h-1 | ||||
环氧环己烷 | 环己二醇 | 其他 | |||||||
W-beta | 2.1 | 49.1 | 44.2 | 6.7 | 77.8 | 2.3 | 99.3 | 85 | |
Mo-beta | 1.0 | 46.9 | 48.6 | 4.5 | 83.3 | 0.9 | 99.3 | 75 | |
V-beta | 25.2 | 30.1 | 44.7 | 25.2 | 160.5 | 13.9 | 99.2 | 88.5 | |
Ti-beta | 20.8 | 50.4 | 43.5 | 6.6 | 76.4 | 16.6 | 99.2 | 61 |
催化剂 | 环己烯 | 环辛烯 | |||||||
转化率/% | 选择性/% | 转换频率(TOF)/h-1 | 转化率/% | 选择性/% | 转换频率(TOF)/h-1 | ||||
环氧环己烷 | 环己二醇 | 其他 | |||||||
W-beta | 2.1 | 49.1 | 44.2 | 6.7 | 77.8 | 2.3 | 99.3 | 85 | |
Mo-beta | 1.0 | 46.9 | 48.6 | 4.5 | 83.3 | 0.9 | 99.3 | 75 | |
V-beta | 25.2 | 30.1 | 44.7 | 25.2 | 160.5 | 13.9 | 99.2 | 88.5 | |
Ti-beta | 20.8 | 50.4 | 43.5 | 6.6 | 76.4 | 16.6 | 99.2 | 61 |
样品名称 | 环己烯 | 环辛烯 | 参考 文献 | ||
---|---|---|---|---|---|
转化率/% | 选择性/% | 转化率/% | 选择性/% | ||
Ti-beta | 20.8 | 50.4 | 16.6 | 99.2 | 本工作 |
Ti-beta-0.015 | 10.9 | 49.5 | [ | ||
Ti-beta-PS | 9.2 | 69.1 | [ | ||
Ti-beta-DT | 16.2 | 68.6 | [ | ||
Ti-beta | 7.7 | 47.4 | [ | ||
Ti-beta | 4.6 | >99 | [ | ||
M-Ti-beta | 6.9 | >99 | [ |
样品名称 | 环己烯 | 环辛烯 | 参考 文献 | ||
---|---|---|---|---|---|
转化率/% | 选择性/% | 转化率/% | 选择性/% | ||
Ti-beta | 20.8 | 50.4 | 16.6 | 99.2 | 本工作 |
Ti-beta-0.015 | 10.9 | 49.5 | [ | ||
Ti-beta-PS | 9.2 | 69.1 | [ | ||
Ti-beta-DT | 16.2 | 68.6 | [ | ||
Ti-beta | 7.7 | 47.4 | [ | ||
Ti-beta | 4.6 | >99 | [ | ||
M-Ti-beta | 6.9 | >99 | [ |
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