Preparation and electrochemical performance of lignin nanoparticles/natural fiber based activated carbon fiber materials

doi:10.16085/j.issn.1000-6613.2021-1797

Abstract

Abstract:

This study was focused on the composite lignin nanoparticles (LNPs) loaded natural fibers, which was by KOH activation to prepare composite porous activated carbon fiber electrode materials. Then the as-prepared activated carbon fiber electrode was tested to evaluate the electrochemical performance in a three-electrode system. The results showed that the specific capacitance of KOH activated carbon fiber electrode material was 351.13F/g at the current density of 0.5A/g, which was much higher than that of non-activated carbon fiber electrode material (7.88F/g) and natural fiber activated carbon fiber material without LNPs (306.50F/g) under the same conditions. In addition, fiber surface loaded with LNPs formed porous activated carbon layer structure during the activation process, which further improved the cyclic stability of the composite activated carbon fiber material. Meanwhile, the abundant hydroxyl of LNPs endowed the composite material with additional pseudocapacitance. After 10000 cycles at a current density of 10A/g, the capacitive retention of the composite activated carbon fiber electrode was still at 95%, which was higher than that of the activated carbon fiber electrode of 87% without LNPs loading. The results indicated that lignin nanoparticles/ natural fiber based activated carbon fiber was an ideal electrode material for supercapacitors. This study also provided a new way for the high-value application of LNPs in biomass carbon fiber as energy storage electrode material.

Key words: activation, potassium hydroxide (KOH), lignin nanoparticles (LNPs), biomass, supercapacitor, electrochemistry

摘要：

以木质素纳米颗粒（LNPs）负载的天然纤维复合材料为研究对象，利用KOH活化的方法对其进行处理制备生物质基复合多孔活性碳纤维电极材料。随后在三电极体系中对合成的复合多孔活性碳纤维电极材料进行了电化学性能测试。研究表明，在0.5A/g的电流密度下，KOH活化的复合碳纤维电极材料的比电容为351.13F/g，远高于相同条件下未活化的复合碳纤维电极材料的比电容（7.88F/g）和未负载LNPs的天然纤维基活性碳纤维材料（306.50F/g）。而且在活化过程中，负载在纤维表面的LNPs会形成多孔的活性碳层结构，这会进一步提高复合活性碳纤维材料的循环稳定性，同时LNPs中丰富的羟基赋予复合材料额外的赝电容。在10A/g的电流密度下经过10000次循环后，复合活性碳纤维电极材料的电容保持率仍然为95%，高于未负载LNPs的活性碳纤维电极材料的电容保持率87%。结果表明，木质素纳米颗粒/天然纤维基活性碳纤维材料是一种理想的电极材料，本研究也为LNPs在生物质碳纤维作为储能电极材料的高值化应用提供了一条新途径。

关键词: 活化, 氢氧化钾, 木质素纳米颗粒, 生物质, 超级电容器, 电化学

CLC Number:

TM53

ZHANG Wei, AN Xingye, LIU Liqin, LONG Yinying, ZHANG Hao, CHENG Zhengbai, CAO Haibing, LIU Hongbin. Preparation and electrochemical performance of lignin nanoparticles/natural fiber based activated carbon fiber materials[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3770-3783.

张伟, 安兴业, 刘利琴, 龙垠荧, 张昊, 程正柏, 曹海兵, 刘洪斌. 木质素纳米颗粒/天然纤维基活性碳纤维材料的制备及其电化学性能[J]. 化工进展, 2022, 41(7): 3770-3783.

Figures/Tables 13

材料名称	材料纯度	生产厂家
天然针叶木浆纤维	—	浙江景兴纸业股份有限公司
木质素	—	实验室碱法蒸煮制浆过程中自提
氢氧化钾（KOH）	分析纯	福晨（天津）化学试剂有限公司
无水乙醇	分析纯	天津市东天正精细化学试剂厂
硫酸（H₂SO₄）	分析纯	天津市风船化学试剂科技有限公司
盐酸（HCl）	分析纯	天津市风船化学试剂科技有限公司
不锈钢网	—	天津安诺合新能源科技有限公司
聚四氟乙烯乳液（质量分数60%）	—	上海麦克林生化科技有限公司
乙炔炭黑	—	上海麦克林生化科技有限公司
氮气	高纯（>99.9%）	天津市军粮城常福气体有限公司

仪器名称	型号	生产厂家
电子分析天平	EL204	梅特勒（上海）有限公司
管式炉	OTF-1200X	合肥科晶仪器有限公司
扫描电子显微镜	JSM-IT300LV	日本电子公司
比表面积和孔径分析仪	BELSORP-max	日本麦奇克拜尔有限公司
同步热分析仪	SDT650	美国TA仪器公司
X射线衍射仪	D8	德国布鲁克公司
X射线光电子能谱仪	Escalab 250Xi+	Thermo Scientific科技公司
手动压片机	769YP-15A	天津市科器高新技术公司
电化学工作站	CHI660	上海辰华有限公司

样品名	材料	活化条件（前体与KOH的比例，m/m）
LF₀	LNPs/天然纤维复合材料	未活化
LFC	LNPs/天然纤维基复合碳纤维材料	未活化
LFC_1∶2	复合多孔生物质活性碳纤维材料	1∶2
LFC_1∶4	复合多孔生物质活性碳纤维材料	1∶4
LFC_1∶6	复合多孔生物质活性碳纤维材料	1∶6
LFC_1∶8	复合多孔生物质活性碳纤维材料	1∶8
LFC_1∶10	复合多孔生物质活性碳纤维材料	1∶10
FC_1∶2	天然纤维基活性碳纤维材料	1∶2
FC_1∶4	天然纤维基活性碳纤维材料	1∶4
FC_1∶6	天然纤维基活性碳纤维材料	1∶6
FC_1∶8	天然纤维基活性碳纤维材料	1∶8
FC_1∶10	天然纤维基活性碳纤维材料	1∶10

样品名	总比表面积/m²?g^-1	微孔比表面积/m²?g^-1	介孔比表面积/m²?g^-1	总孔容/cm³?g^-1	微孔孔容/cm³?g^-1	介孔孔容/cm³?g^-1
LFC	312.97	134.10	178.87	0.2658	0.0611	0.2047
LFC_1∶8	2187.10	1820.14	366.96	1.1798	0.7604	0.4194
FC_1∶8	3274.0	2196.2	1077.8	1.6719	0.9075	0.7644

样品	C 1s/%			O 1s/%
样品	C―C	C―O	C $? ????$ O	C $? ????$ O	O $? ????$ C―O―C $? ????$ O
LFC	65.0	29.5	5.5	53.8	46.2
LFC_1∶8	47.2	24.5	28.3	52.8	47.2
FC_1∶8	48.9	23.0	28.1	50.2	49.8

样品	C 1s/%			O 1s/%
样品	C―C	C―O	C $? ????$ O	C $? ????$ O	O $? ????$ C―O―C $? ????$ O
LFC	65.0	29.5	5.5	53.8	46.2
LFC_1∶8	47.2	24.5	28.3	52.8	47.2
FC_1∶8	48.9	23.0	28.1	50.2	49.8

样品	C	O	N	P	S
LFC	88.92	7.66	3.03	0.17	0.22
LFC_1∶8	91.71	6.52	0.95	0.27	0.55
FC_1∶8	87.56	10.42	1.30	0.40	0.31

References 57

1	XU Yuandong, ZHANG Yujun. Synthesis of polypyrrole/sodium carboxymethyl cellulose nanospheres with enhanced supercapacitor performance[J]. Materials Letters, 2015, 139: 145-148.
2	LIU Panbo, YAN Jing, GUANG Zhaoxu, et al. Recent advancements of polyaniline-based nanocomposites for supercapacitors[J]. Journal of Power Sources, 2019, 424: 108-130.
3	WANG Zhaohui, CARLSSON Daniel O, TAMMELA Petter, et al. Surface modified nanocellulose fibers yield conducting polymer-based flexible supercapacitors with enhanced capacitances[J]. ACS Nano, 2015, 9(7): 7563-7571.
4	KHOSROZADEH Ali, DARABI Mohammad Ali, XING Malcolm, et al. Flexible electrode design: fabrication of freestanding polyaniline-based composite films for high-performance supercapacitors[J]. ACS Applied Materials & Interfaces, 2016, 8(18): 11379-11389.
5	LIU Xianbin, LAI Changgan, XIAO Zechen, et al. Superb electrolyte penetration/absorption of three-dimensional porous carbon nanosheets for multifunctional supercapacitor[J]. ACS Applied Energy Materials, 2019, 2(5): 3185-3193.
6	WANG Li, YU Jie, DONG Xuantong, et al. Three-dimensional macroporous carbon/Fe₃O₄-doped porous carbon nanorods for high-performance supercapacitor[J]. ACS Sustainable Chemistry & Engineering, 2016, 4(3): 1531-1537.
7	TAN Yueming, XU Chaofa, CHEN Guangxu, et al. Synthesis of ultrathin nitrogen-doped graphitic carbon nanocages as advanced electrode materials for supercapacitor[J]. ACS Applied Materials & Interfaces, 2013, 5(6): 2241-2248.
8	YAHYA M A, AL-QODAH Z, NGAH C W Z. Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: a review[J]. Renewable and Sustainable Energy Reviews, 2015, 46: 218-235.
9	ZHANG Lei, HU Xiaosong, WANG Zhenpo, et al. A review of supercapacitor modeling, estimation, and applications: a control/management perspective[J]. Renewable and Sustainable Energy Reviews, 2018, 81: 1868-1878.
10	WANG Yiliang, CHANG Binbin, GUAN Daxiang, et al. Mesoporous activated carbon spheres derived from resorcinol-formaldehyde resin with high performance for supercapacitors[J]. Journal of Solid State Electrochemistry, 2015, 19(6): 1783-1791.
11	CHEN Haichao, JIANG Jianjun, ZHANG Li, et al. Facilely synthesized porous NiCo₂O₄ flowerlike nanostructure for high-rate supercapacitors[J]. Journal of Power Sources, 2014, 248: 28-36.
12	ABIOYE Adekunle Moshood, Farid Nasir ANI. Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: a review[J]. Renewable and Sustainable Energy Reviews, 2015, 52: 1282-1293.
13	VOLPERTS Aleksandrs, PLAVNIECE Ance, DOBELE Galina, et al. Biomass based activated carbons for fuel cells[J]. Renewable Energy, 2019, 141: 40-45.
14	SU Xiaoli, CHENG Mingyu, FU Lin, et al. Superior supercapacitive performance of hollow activated carbon nanomesh with hierarchical structure derived from poplar catkins[J]. Journal of Power Sources, 2017, 362: 27-38.
15	SU Xiaoli, LI Shuaihui, JIANG Shuai, et al. Superior capacitive behavior of porous activated carbon tubes derived from biomass waste-cotonier strobili fibers[J]. Advanced Powder Technology, 2018, 29(9): 2097-2107.
16	董仕安. 生物质基碳材料的表面修饰及其电化学性能研究[D]. 马鞍山: 安徽工业大学, 2018.
	DONG Shi’an. Surface modification of biomass-derived carbons and their electrochemical properties[D]. Maanshan: Anhui University of Technology, 2018.
17	王帅, 甘林火, 吕丽. 木质素基介孔碳材料的制备及应用进展[J]. 化工进展, 2019, 38(8): 3720-3729.
	WANG Shuai, GAN Linhuo, Li LYU. Progress in preparation and application of lignin-derived mesoporous carbon materials[J]. Chemical Industry and Engineering Progress, 2019, 38(8): 3720-3729.
18	曾茂株, 佘煜琪, 胡玉彬, 等. 木质素多孔炭的制备及应用研究进展[J]. 化工进展, 2021, 40(8): 4573-4586.
	ZENG Maozhu, SHE Yuqi, HU Yubin, et al. Progress in preparation and application of lignin porous carbon[J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4573-4586.
19	GARCÍA-MATEOS FRANCISCO José, Ramiro RUIZ-ROSAS, MARÍA Rosas Juana, et al. Activation of electrospun lignin-based carbon fibers and their performance as self-standing supercapacitor electrodes[J]. Separation and Purification Technology, 2020, 241: 116724.
20	PENG Zhiyuan, ZOU Yubo, XU Shiqi, et al. High-performance biomass-based flexible solid-state supercapacitor constructed of pressure-sensitive lignin-based and cellulose hydrogels[J]. ACS Applied Materials & Interfaces, 2018, 10(26): 22190-22200.
21	CAO Qiping, ZHU Mengni, CHEN Jiaai, et al. Novel lignin-cellulose-based carbon nanofibers as high-performance supercapacitors[J]. ACS Applied Materials & Interfaces, 2020, 12(1): 1210-1221.
22	SCHLEE Philipp, HEROU Servann, JERVIS Rhodri, et al. Free-standing supercapacitors from Kraft lignin nanofibers with remarkable volumetric energy density[J]. Chemical Science, 2019, 10(10): 2980-2988.
23	LIU Tao, REN Xinle, ZHANG Junmei, et al. Highly compressible lignin hydrogel electrolytes via double-crosslinked strategy for superior foldable supercapacitors[J]. Journal of Power Sources, 2020, 449: 227532.
24	JEON Ju Won, ZHANG Libing, LUTKENHAUS Jodie L, et al. Controlling porosity in lignin-derived nanoporous carbon for supercapacitor applications[J]. ChemSusChem, 2015, 8(3): 428-432.
25	LIU Wanshuang, YAO Yimin, FU Ouli, et al. Lignin-derived carbon nanosheets for high-capacitance supercapacitors[J]. RSC Advances, 2017, 7(77): 48537-48543.
26	熊福全, 韩雁明, 王思群, 等. 纳米木质素的制备及应用研究现状[J]. 高分子材料科学与工程, 2016, 32(12): 156-161.
	XIONG Fuquan, HAN Yanming, WANG Siqun, et al. Progress of preparation and application of lignin nanoparticles[J]. Polymer Materials Science and Engineering, 2016, 32(12): 156-161.
27	LIU Xiaoguang, MA Changde, LI Jiaxin, et al. Biomass-derived robust three-dimensional porous carbon for high volumetric performance supercapacitors[J]. Journal of Power Sources, 2019, 412: 1-9.
28	WANG Kai, ZHAO Ning, LEI Shiwen, et al. Promising biomass-based activated carbons derived from willow catkins for high performance supercapacitors[J]. Electrochimica Acta, 2015, 166: 1-11.
29	SONG Shijiao, MA Fangwei, WU Guang, et al. Facile self-templating large scale preparation of biomass-derived 3D hierarchical porous carbon for advanced supercapacitors[J]. Journal of Materials Chemistry A, 2015, 3(35): 18154-18162.
30	LIN Gaoxin, MA Ruguang, ZHOU Yao, et al. KOH activation of biomass-derived nitrogen-doped carbons for supercapacitor and electrocatalytic oxygen reduction[J]. Electrochimica Acta, 2018, 261: 49-57.
31	HE Jingjing, ZHANG Deyi, HAN Mei, et al. One-step large-scale fabrication of nitrogen doped microporous carbon by self-activation of biomass for supercapacitors application[J]. Journal of Energy Storage, 2019, 21: 94-104.
32	WANG Yulin, QU Qingli, GAO Shuting, et al. Biomass derived carbon as binder-free electrode materials for supercapacitors[J]. Carbon, 2019, 155: 706-726.
33	SU Xiaoli, CHEN Jingran, ZHENG Guangping, et al. Three-dimensional porous activated carbon derived from loofah sponge biomass for supercapacitor applications[J]. Applied Surface Science, 2018, 436: 327-336.
34	SAHA Dipendu, LI Yunchao, BI Zhonghe, et al. Studies on supercapacitor electrode material from activated lignin-derived mesoporous carbon[J]. Langmuir, 2014, 30(3): 900-910.
35	SHANG Zhen, AN Xingye, LIU Liqin, et al. Chitin nanofibers as versatile bio-templates of zeolitic imidazolate frameworks for N-doped hierarchically porous carbon electrodes for supercapacitor[J]. Carbohydrate Polymers, 2021, 251: 117107.
36	RAYMUNDO-PIÑERO E, AZAÏS P, CACCIAGUERRA T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation[J]. Carbon, 2005, 43(4): 786-795.
37	LI Yubing, ZHANG Deyi, ZHANG Yameng, et al. Biomass-derived microporous carbon with large micropore size for high-performance supercapacitors[J]. Journal of Power Sources, 2020, 448: 227396.
38	WANG Jiacheng, KASKEL Stefan. KOH activation of carbon-based materials for energy storage[J]. Journal of Materials Chemistry, 2012, 22(45): 23710-23725.
39	ROMANOS J, BECKNER M, RASH T, et al. Nanospace engineering of KOH activated carbon[J]. Nanotechnology, 2012, 23(1): 15401.
40	BORENSTEIN Arie, HANNA Ortal, ATTIAS Ran, et al. Carbon-based composite materials for supercapacitor electrodes: a review[J]. Journal of Materials Chemistry A, 2017, 5(25): 12653-12672.
41	Noel DÍEZ, FERRERO Guillermo A, SEVILLA Marta, et al. A sustainable approach to hierarchically porous carbons from tannic acid and their utilization in supercapacitive energy storage systems[J]. Journal of Materials Chemistry A, 2019, 7(23): 14280-14290.
42	曲可琪, 尤月, 孙哲, 等. 氮硼掺杂菌糠炭：蜂窝结构用于电极材料[J]. 化工进展, 2021, 40(3): 1527-1536.
	QU Keqi, YOU Yue, SUN Zhe, et al. N, B-doped carbon from fungus bran: honeycomb structure as electrode material[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1527-1536.
43	SHANG Zhen, AN Xingye, ZHANG Hao, et al. Houttuynia-derived nitrogen-doped hierarchically porous carbon for high-performance supercapacitor[J]. Carbon, 2020, 161: 62-70.
44	ZHANG Xiudong, BAI Yuanyuan, CAO Xuefei, et al. Pretreatment of Eucalyptus in biphasic system for furfural production and accelerated enzymatic hydrolysis[J]. Bioresource Technology, 2017, 238: 1-6.
45	ZHANG Weijie, CHEN Zhongtao, GUO Xinli, et al. N/S co-doped three-dimensional graphene hydrogel for high performance supercapacitor[J]. Electrochimica Acta, 2018, 278: 51-60.
46	WANG Yahui, LIU Ruonan, TIAN Yadong, et al. Heteroatoms-doped hierarchical porous carbon derived from chitin for flexible all-solid-state symmetric supercapacitors[J]. Chemical Engineering Journal, 2020, 384: 123263.
47	GAO Shuyan, LI Xiaoge, LI Lingyu, et al. A versatile biomass derived carbon material for oxygen reduction reaction, supercapacitors and oil/water separation[J]. Nano Energy, 2017, 33: 334-342.
48	CHEN Wei, LI Kaixu, CHEN Zhiqun, et al. A new insight into chemical reactions between biomass and alkaline additives during pyrolysis process[J]. Proceedings of the Combustion Institute, 2021, 38(3): 3881-3890.
49	JI Linlin, WANG Bin, YU Yanling, et al. N, S co-doped biomass derived carbon with sheet-like microstructures for supercapacitors[J]. Electrochimica Acta, 2020, 331: 135348.
50	李诗杰, 韩奎华. 活性炭孔结构及电化学性能协同优化[J]. 化工进展, 2020, 39(1): 287-293.
	LI Shijie, HAN Kuihua. Synergistic optimization of pore structure and electrochemical properties of activated carbon[J]. Chemical Industry and Engineering Progress, 2020, 39(1): 287-293.
51	CHEN Mingfeng, YU Dan, ZHENG Xiaozhong, et al. Biomass based N-doped hierarchical porous carbon nanosheets for all-solid-state supercapacitors[J]. Journal of Energy Storage, 2019, 21: 105-112.
52	WAN Mimi, SUN Xiaodan, LI Yanyan, et al. Facilely fabricating multifunctional N-enriched carbon[J]. ACS Applied Materials & Interfaces, 2016, 8(2): 1252-1263.
53	LI Aijun, CHUAN Xiuyun, YANG Yang, et al. Influence of activated condition on the structure of diatomite-templated carbons and their electrochemical properties as supercapacitors[J]. Electrochemistry, 2017, 85(11): 708-714.
54	ZHANG Guoxiong, CHEN Yuemei, CHEN Yigang, et al. Activated biomass carbon made from bamboo as electrode material for supercapacitors[J]. Materials Research Bulletin, 2018, 102: 391-398.
55	YIN Weiming, TIAN Linfei, PANG Bo, et al. Fabrication of dually N/S-doped carbon from biomass lignin: porous architecture and high-rate performance as supercapacitor[J]. International Journal of Biological Macromolecules, 2020, 156: 988-996.
56	TANG Diyong, LUO Yanyue, LEI Weidong, et al. Hierarchical porous carbon materials derived from waste lentinus edodes by a hybrid hydrothermal and molten salt process for supercapacitor applications[J]. Applied Surface Science, 2018, 462: 862-871.
57	LI Xing, TANG Yao, SONG Junhua, et al. Self-supporting activated carbon/carbon nanotube/reduced graphene oxide flexible electrode for high performance supercapacitor[J]. Carbon, 2018, 129: 236-244.

[1]	ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.
[2]	HU Xi, WANG Mingshan, LI Enzhi, HUANG Siming, CHEN Junchen, GUO Bingshu, YU Bo, MA Zhiyuan, LI Xing. Research progress on preparation and sodium storage properties of tungsten disulfide composites [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 344-355.
[3]	ZHANG Jie, BAI Zhongbo, FENG Baoxin, PENG Xiaolin, REN Weiwei, ZHANG Jingli, LIU Eryong. Effect of PEG and its compound additives on post-treatment of electrolytic copper foils [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 374-381.
[4]	CHENG Tao, CUI Ruili, SONG Junnan, ZHANG Tianqi, ZHANG Yunhe, LIANG Shijie, PU Shi. Analysis of impurity deposition and pressure drop increase mechanisms in residue hydrotreating unit [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4616-4627.
[5]	WANG Jingang, ZHANG Jianbo, TANG Xuejiao, LIU Jinpeng, JU Meiting. Research progress on modification of Cu-SSZ-13 catalyst for denitration of automobile exhaust gas [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4636-4648.
[6]	WANG Yaogang, HAN Zishan, GAO Jiachen, WANG Xinyu, LI Siqi, YANG Quanhong, WENG Zhe. Strategies for regulating product selectivity of copper-based catalysts in electrochemical CO₂ reduction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4043-4057.
[7]	LIU Yi, FANG Qiang, ZHONG Dazhong, ZHAO Qiang, LI Jinping. Cu facets regulation of Ag/Cu coupled catalysts for electrocatalytic reduction of carbon dioxide [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4136-4142.
[8]	ZHANG Yajuan, XU Hui, HU Bei, SHI Xingwei. Preparation of NiCoP/rGO/NF electrocatalyst by eletroless plating for efficient hydrogen evolution reaction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4275-4282.
[9]	WANG Shuaiqing, YANG Siwen, LI Na, SUN Zhanying, AN Haoran. Research progress on element doped biomass carbon materials for electrochemical energy storage [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4296-4306.
[10]	ZHANG Yaojie, ZHANG Chuanxiang, SUN Yue, ZENG Huihui, JIA Jianbo, JIANG Zhendong. Application of coal-based graphene quantum dots in supercapacitors [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4340-4350.
[11]	WU Ya, ZHAO Dan, FANG Rongmiao, LI Jingyao, CHANG Nana, DU Chunbao, WANG Wenzhen, SHI Jun. Research progress on highly efficient demulsifiers for complex crude oil emulsions and their applications [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4398-4413.
[12]	ZHENG Mengqi, WANG Chengye, WANG Yan, WANG Wei, YUAN Shoujun, HU Zhenhu, HE Chunhua, WANG Jie, MEI Hong. Application and prospect of algal-bacterial symbiosis technology in zero liquid discharge of industrial wastewater [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4424-4431.
[13]	LI Haidong, YANG Yuankun, GUO Shushu, WANG Benjin, YUE Tingting, FU Kaibin, WANG Zhe, HE Shouqin, YAO Jun, CHEN Shu. Effect of carbonization and calcination temperature on As(Ⅲ) removal performance of plant-based Fe-C microelectrolytic materials [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3652-3663.
[14]	GUAN Hongling, YANG Hui, JING Hongquan, LIU Yuqiong, GU Shouyu, WANG Haobin, HOU Cuihong. Lignin-based controlled release materials and application in drug delivery and fertilizer controlled-release [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3695-3707.
[15]	LI Yanling, ZHUO Zhen, CHI Liang, CHEN Xi, SUN Tanglei, LIU Peng, LEI Tingzhou. Research progress on preparation and application of nitrogen-doped biochar [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3720-3735.