Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (4): 2130-2137.DOI: 10.16085/j.issn.1000-6613.2020-1012

• Energy processes and technology • Previous Articles     Next Articles

Oxidization-modification and thermal conversion behavior of ethylene tar pitch

ZHAO Chunlei1(), ZHU Yaming1,2(), GAO Lijuan1, CHENG Junxia1, LAI Shiquan1, ZHAO Xuefei1,2()   

  1. 1.Engineering Research Center of Advanced Coal Coking and Efficient Use of Coal Resources, University of Science and Technology Liaoning, Institute of Chemical Engineering, Anshan 114051, Liaoning, China
    2.Key Laboratory of Chemical Metallurgy Liaoning Province’, University of Science and Technology Liaoning, Anshan 114051, Liaoning, China
  • Received:2020-06-08 Online:2021-04-14 Published:2021-04-05
  • Contact: ZHU Yaming,ZHAO Xuefei

乙烯渣油沥青的氧化改性及其热转化行为

赵春雷1(), 朱亚明1,2(), 高丽娟1, 程俊霞1, 赖仕全1, 赵雪飞1,2()   

  1. 1.辽宁科技大学化工学院,辽宁省先进煤焦化及煤资源高效利用工程研究中心,辽宁 鞍山 114051
    2.辽宁科技 大学,辽宁省化学冶金重点实验室,辽宁 鞍山 114051
  • 通讯作者: 朱亚明,赵雪飞
  • 作者简介:赵春雷(1994—),男,硕士研究生,研究方向沥青基炭材料。E-mail:zhaochunlei0506@126.com
  • 基金资助:
    国家自然科学基金(U1361126);辽宁省自然科学基金(20180551218);辽宁省教育厅项目(2017LNQN04);辽宁科技大学优秀人才培养项目(2018RC07);辽宁科技大学青年基金(2017QN06)

Abstract:

Ethylene tar pitch with high aromaticity and good physical-chemical properties has been widely used as the raw materials for the production of artificial carbon materials. To fully understand the thermal conversion behaviors of ethylene tar pitch is important to the production of high-quality carbon materials from the ethylene tar pitch. In this paper, the thermal conversion of the ethylene tar pitch (ETP) and two atmospheric air oxidation modified pitches (MP1 and MP2) was examined and monitored by elemental analyzer, FTIR, TGA, polarized microscope, SEM, XRD and Raman spectroscopy. The results showed that the thermal-stability and content of C?????O and C—O groups of the modified pitches were significantly higher than those of the ethylene tar pitch. The C?????O groups functioned as the reactive site can initiate the thermal reactions. The constant temperature treatment conditions were beneficial to the formation of fibrous structure in the pitch coke, and the content of leaflet structure was relatively higher in the pitch coke under the variable temperature treatment conditions. The regularity of the carbon microcrystallites of the modified pitch coke was lower than that of the ethylene tar pitch coke.

Key words: ethylene tar pitch, thermal conversion behavior, microstructure

摘要:

乙烯渣油沥青具有较高的芳香度和良好的理化性质,有可能作为制备高品质人造炭材料的原料。充分了解和认识乙烯渣油沥青热转化行为是制备高品质乙烯渣油沥青基炭材料的关键。本文研究了乙烯渣油沥青(ETP)及常压空气氧化改性沥青(MP1和MP2)在恒温和变温条件下的热转化行为,用元素分析、FTIR、TGA、偏光显微镜、SEM、XRD、Raman光谱等方法,研究了三种沥青在热转化过程中的结构和性质变化规律。发现改性沥青的热稳定性、C?????O和C—O含量均明显高于乙烯渣油沥青。热转化过程中,沥青分子中的C?????O官能团作为反应活性位点诱导热转化反应的发生。恒温热转化有利于热转化产物中纤维状结构的形成,变温热转化使得沥青焦显微结构中片状组分含量相对较高。改性沥青焦的碳微晶排列规整程度均低于乙烯渣油沥青焦的碳微晶排列规整程度。

关键词: 乙烯渣油沥青, 热转化行为, 微观结构

CLC Number: 

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