化工进展 ›› 2015, Vol. 34 ›› Issue (08): 3202-3206.DOI: 10.16085/j.issn.1000-6613.2015.08.047

• 应用技术 • 上一篇    

二步法氧化焙烧工业绿矾工艺

张海平1,2, 郝建璋2, 黎建明2, 丁跃华1, 李宏扬1,2   

  1. 1 昆明理工大学冶金与能源工程学院, 云南 昆明 650024;
    2 攀钢集团研究院有限公司钒钛资源综合利用国家重点实验室, 四川 攀枝花 617000
  • 收稿日期:2014-12-26 修回日期:2015-01-16 出版日期:2015-08-05 发布日期:2015-08-05
  • 通讯作者: 郝建璋,工程硕士,高级工程师,研究方向为固体废弃物资源综合利用。E-mail hjz980809@126.com
  • 作者简介:张海平(1989—),男,硕士研究生。E-mail zhpkmu@163.com。

Oxidizing calcination industry copperas by two-step method

ZHANG Haiping1,2, HAO Jianzhang2, LI Jianming2, DING Yuehua1, LI Hongyang1,2   

  1. 1 College of Metallurgy and Energy Engineering, Kumming University of Science and Technology, Kunming 650024, Yunnan, China;
    2 State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Pangang Group Research Institute Co., Ltd., Panzhihua 617000, Sichuan, China
  • Received:2014-12-26 Revised:2015-01-16 Online:2015-08-05 Published:2015-08-05

摘要: 为提高绿矾综合利用效率,实现节能环保生产,研究了二步法氧化焙烧工艺。第一步,对绿矾进行干燥脱水处理研究,通过对绿矾干燥脱水曲线及TG-DSC曲线的分析可知,绿矾前期干燥脱水的最佳温度为110℃,此时所得产物大部分为FeSO4·7H2O;第二步,在不同温度下通空气对第一步的干燥产物进行氧化焙烧,研究了焙烧温度对焙烧产物回收率、残硫量、Fe化合形态及烟气中硫分布的影响,结果在800~900℃、气流量120L/h、恒温时间90min的条件下,最终所得焙烧产物的残硫量为0.33%,总铁(TFe)在60%以上,可以作为炼铁原料配加进入烧结矿,且烟气中的硫得到了回收。

关键词: 二步法, 氧化焙烧, 绿矾

Abstract: This paper studied a two-step method of oxidizing calcination process in order to improve the utilization efficiency of copperas and achieve the energy-saving and environmental production. The analysis of copperas' drying and dehydration curves and TG-DSC (thermogravimetric analysis and differential scanning calarmeutry) curves showed that the best drying temperature was 110℃, and most of the product was FeSO4·7H2O. Then the dried products were calcinated at the different temperature. The influences of the calcination temperature on the product recovery, residual sulfur content, the compound morphology of Fe and the distribution of sulfur in the flue gas was investigated. The results showed that when the temperature was 800—900℃, air flow rate was 120L/h, and the constant temperature time was 90min, the amount of residual sulfur in the calcinated product was 0.33% and total Fe was more than 60%. Therefore, the final product could be added into the sinter as iron materials.

Key words: two steps, oxidizing roasting, copperas

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