化工进展 ›› 2015, Vol. 34 ›› Issue (08): 3019-3026,3117.DOI: 10.16085/j.issn.1000-6613.2015.08.018

• 能源加工与技术 • 上一篇    下一篇

委内瑞拉减黏调和油的储存输运稳定性

张娜   

  1. 华侨大学化工学院, 福建 厦门 361021
  • 收稿日期:2015-01-16 修回日期:2015-02-09 出版日期:2015-08-05 发布日期:2015-08-05
  • 作者简介:张娜(1980—),女,讲师,博士,主要从事重质油加工方面的研究。E-mail zhangna@hqu.edu.cn。
  • 基金资助:
    2013年福建省自然科学基金计划项目资助(项目编号:2013J05076)及华侨大学科研基金资助项目(11BS101)。

Storage and transport stability of Venezuela visbreaking blended oil

ZHANG Na   

  1. College of Chemical Engineering, Huaqiao University, Xiamen 361021, Fujian, China
  • Received:2015-01-16 Revised:2015-02-09 Online:2015-08-05 Published:2015-08-05

摘要: 通过考察委内瑞拉常渣减黏调和油黏度、密度、残炭和组成的变化,研究了调和油的长期储存稳定性。通过酸值、胶质和沥青质的结构变化,研究了影响调和油长期储存稳定性的因素。结果表明,不同反应条件下的调和油上下层的黏度、密度和残炭差异不显著,基本相同,调和油没有发生分层现象,长期储存稳定性较好,满足船运要求。随着反应苛刻度和储存时间的增加,胶质/沥青质之比减小,调和油的稳定性下降。溶解在调和油中的微量氧与调和油中的自由基和烯烃发生反应,使得酸值增加。储存过程中胶质和沥青质均发生了缩合,不同反应苛刻度下,4个减黏调和油的胶质结构差异并不大,但420℃/30min调和油沥青质的缩合较明显。氧化反应和胶质、沥青质的缩合使得调和油的长期储存稳定性下降。

关键词: 储存稳定性, 减黏调和油, 黏度, 沥青质, 石油

Abstract: In order to choose a suitable method for ultra-low temperature refrigeration system from two-staged compression and cascade compression, the two refrigeration systems' technical characteristics were analyzed comparatively using theoretical calculations of two-stage and cascade refrigeration system. Both theoretical displacement and theoretical coefficient of the two systems were compared in the economic aspect. Results indicated that compared to two-stage system, compression ratio and exhaust temperature of cascade system were lower and suction pressure and cooling coefficient were higher. At condensing temperature 40℃ and evaporation temperature -65℃, the energy consumption reduction of cascade system can reach to 15.13%, indicating that the performance of cascade system could be better in the ultra-low temperature condition.

Key words: storage stability, visbreaking blended oil, viscosity, asphaltene, petroleum

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